Lee will appear in the fifth season's seventh episode where, according to the info I have, "Chuck encounters Stan Lee in the most unexpected of places," a setting that might suggest The Man has "a secret identity of his own."
"Chuck" co-creator Chris Fedak said, "To say we're excited to have Stan Lee join us on the show is an understatement. His iconic characters and the epic worlds he imagined have been inspirations to all of us working on 'Chuck.'"
Read more at Hitfix
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